The propellant combinations WFNA/ JP-4 and later IRFNA/JP-4 were the first storable systems given serious consideration in the United States. Problems which caused the abandoning of these propellants were the absence of reliable hypergolic ignition and unstable combustion. IRFNA/UDMH and IRFNA/JP-X finally did prove satisfactory.
The composition of propellant-grade nitric acids is covered by Military Specification MIL-N-7254. The nitric acids are fuming liquids which vary from colorless to brown, depending on the amount of dissolved N2O4. The vapours from these acids have a characteristic pungent odour. They are highly corrosive, toxic, oxidising agents and attack most metals. They react with most organic materials violently enough to cause fire. The acids are soluble in water in all proportions, with an accompanying evolution of heat. They cannot be made to explode. Approximately 90 per cent of the nitric acid is made by the catalytic oxidation of ammonia with air or oxygen to yield nitric oxide (NO). The latter is oxidised to N2O4 which, when treated with water, yields nitric acid (HNO3) and may be concentrated by distillation with sulphuric acid. Red fuming nitric acids may be produced by passing gaseous N2O4 into nitric acid, a slight modification of the above process. Production of nitric acid was estimated at 3 million tonnes in 1959. The price of RFNA was $ 0.20 per kg in drum lots; IRFNA was slightly higher. The varieties of nitric acid propellants include:
It is a relatively high-boiling gas with a vapour pressure of 8.7 bar at 20 deg C. Ammonia. is toxic, and will dissolve easily in water. It will form flammable and explosive mixtures with air. Although ammonia itself is toxic, the exhaust gases from the combustion of ammonia and oxygen are not. Ammonia is produced by a Haber-Bosch process, in which the elements, nitrogen and hydrogen, are united at a temperature of 500 to 600 deg C and a. pressure of approximately 200 bar in the presence of a promoted iron catalyst. It is estimated that 4 million tonnes of anhydrous synthetic ammonia were produced in 1959 in the United States, at which time the price of tank-car quantities of refrigeration-grade anhydrous ammonia was $ 80 per tonne.
Oxidizer: Nitric acid. Fuel: Ammonia. Propellant Formulation: IRFNA/Ammonia. Optimum Oxidizer to Fuel Ratio: 2.1. Temperature of Combustion: 2,690 deg K. Ratio of Specific Heats: 1.24. Density: 1.10 g/cc. Characteristic velocity c: 1,610 m/s (5,280 ft/sec). Isp Shifting: 260 sec. Isp Frozen: 255 sec. Mol: 21.00 M (68.00 ft). Oxidizer Density: 1.510 g/cc. Oxidizer Freezing Point: -42 deg C. Oxidizer Boiling Point: 86 deg C. Fuel Density: 0.604 g/cc. Fuel Freezing Point: -78 deg C. Fuel Boiling Point: -33 deg C.
Specific impulse: 255 s.